Hi Dr. Bob.
I just had my first pH crash and after researching everything possible to fix and recover from it I now have a BRAIN OVERLOAD. Carolyn from Microbe-Lift sent me your web link to get some answers from a pro (thus-YOU).
I’m in Charlotte NC and 9 yrs ago I built a 4000 gal Koi pond and have 9 Koi (18-24’’) left ( born in the pond, hand feed and named), I also have 15 goldfish. I have a 200 gal media filter box and a 200 gal bio filter box both with up flow water that goes back to the pond. I also have a waterfall, UV light, skimmer and everything is running on two 5000 gph pumps with plenty of circulation. I faithfully clean out mechanical filter and do a 10-15% water change ever week using ML/Xtreme for conditioner (after pH crash I will also continue them through the winter months). I have never had a problem with the pond until pH crashed (a ton of rain) 2 weeks ago and lost 4 of my biggest Kio. With the cold weather and holidays I’m embarrassed to say the pond gets neglected for a couple months in winter. Now I need some help to recover from this.
I’ve been using baking soda to bring pH and KH levels up, I also put 50 Lbs of crushed oyster shells in filter box to help maintain levels. I also put 30 lbs of crushed coral in filter box to help with pH, not sure if 30lbs is enough to do anything to pH levels. With the baking soda additions came ammonia spikes so I started doing water changes, 10-15% a day for 4 days. Went from 3.0 to 0.50 but know I’m noticing that nitrate levels that were 0 are also going up.
Tap water test, pH/6.8 or a little lower, KH/40, GH/25.
Pond water test today, pH/7.2, KH/80-100, GH/75, Nitrite/0, Nitrate/20, and Ammonia/0.50
These are the only products I’ve ever used in my pond. Microbe lift/Xtreme for water conditioner and chloramines (tap water is treated with chloramines), ML/PL to help keep healthy pond and bio filter, ML/liquid barley (not with peat), and baking soda.
I just started using crushed oyster shells and by Carolyn’s suggestion and ML/Nite-out ll for ammonia and nitrite oxidation. The water temp on Friday was 48 but we are suppose to be in the upper to lower 20’s at night for the next 10 days (thank goodness days are much warmer) so I’m not sure how well ML/nite-out ll is going to work because it said to start using at 55. I also order Koizyme to help out with aeromonas alley which I’m sure will be a problem in spring after having a pH crash and I’m sure the crash has killed my filters.
So my question is how do I fix it? This is what I THINK I know from all the brain overload research. Ammonia levels are not as toxic in cold water but I’m concerned about when the weather warms up and bio filter starting over (with big fish in pond). How do I keep ammonia levels down and nitrite and nitrate levels going up without water changes every day? Is there a product you would recommend or will the ML/nite-out ll work? I also picked up a gal of kordon AmQuel plus at petsmart it’s an ammonia detoxifier, I haven’t used it yet because I’m not sure. I also read that salt will help, 1lb for 100 gals for me that’s 40 lbs. When should I put it in pond and for how long, is this the right amount and what kind of salt can I use. I’ve read that it can be salt for water softeners or rock salt (there is no where to get that much pond salt around here and price is very high for pond salt online). I’m also concerned about pH, KH and GH levels being low out of tap, how often can I use baking soda (adding 1/3 cup per 1000 gals). I also know that using baking soda raises the pH and higher pH leads to ammonia spikes. But I need the baking soda to raise the KH to keep the pH from falling to low. I just put in 50lbs of crushed oyster shells and I know they take a while to stabilize is 50lbs ok and how often should I replace them? GH is also low and from what I’ve read it works better a little higher for Koi, what should I use to raise it if anything.
I’m sure I forgot to ask something and I’m so sorry about the BOOK, but as they say “Knowledge is Power” and I could use a little of that power right know. Thank you
Deb
Okay, I'll try to take these in order.
1) How much drop in pH is a "crash"? You have to remember that pH is the reverse log of the hydrogen ion concentration. That means that a change of 1.0 in the pH reflects a tenfold change in the [H+]. A change of 2.0 is 100-fold! Usual water pH out of the tap around here is between 7.5 to 8.5, depending on the water source. Your pH of 6.2 reflected a sudden increase in acidity of nearly 100-fold. In fact, any sudden change in pH more than 0.1 is enough to impact your fish and filter. The reason for the crash was your KH. (Stands for "Karbonate" hardness {those sneaky Germans!}) We in the frozen North call it "alkalinity", also a misnomer. It is your pond's ability to resist changes in pH and should NEVER drop below 80-90ppm. Water out of the tap around here runs about 120ppm.
2) Plaster of Paris. Get it from the craft store. It'll be purer calcium salts. The Dap stuff is strengthened to handle patching jobs. The craft stuff isn't. You use as many of the pucks as you need to keep your alkalinity up above 100.
3) Solar salt. Look at the bag. If it says "99.mumblemumble % pure solar salt, it's good. Avoid pelletized or treated products. They are not fish friendly. For guidance in their use, go to the MPKS website for the salt formulae and the article I mentioned. Your fish can handle up to 3 lbs/100 gallons for several weeks without too much stress, and 1.5 lbs /100 gallons almost indefinitely. Your beautiful plants will die at the higher salt levels (3.8ppt) but can handle the lower concentrations (1.88ppt). Do not use salt unless you see the nitrite begin to spike up. It will start to rise as the ammonia begins to fall. Your pond's biofiltration will begin to rev up as your water temp approaches 50 F. At 55 F you'll see the ammonia begin to drop and the nitrite begin to rise. DO NOT FEED THE FISH! Salt up gradually over two or three days and watch the nitrites. As they begin to drop, you can start to wash down the salt levels with water changes. Do not use salt without a reliable way of testing for it. Do not use ANY formaldehyde-containing anti-parasitics in cold water or water with salt in it.
4) Never NEVER throw away instruction sheets!
Bob
Bob,
Thank you so much for responding so quickly, you help is greatly appreciated!
First I want to say that I’m not exactly sure it was a pH crash because I’m not sure what the definition of a pH crash is. After the first 2 fish died and I wrote to Carolyn from Microbe-Lift because I thought it was some kind of illness. As she asked I went out to test the pond and that is when she suggested a pH crash.
When I tested the pH was very close to 6.2 and the KH/40, does that mean pH crash. And at what pH number does it completely kill off my filter?
I went to Lowes today to look at plaster of Paris; they have Dap in a 25lb box for $16. The ingredients are calcium sulfate, hemihydrate, calcium carbonate & crystalline silica is this ok to use or is there something different at the craft stores? You said I can throw a few in pond and they will dissolve in a week or two, when they dissolve do I throw in a few more and continue to do that each time they dissolve or only when KH gets low? Do they make pond look mucky after all it is a type of drywall mud. This idea sure sounds a lot easier than the heavy 50lbs of crushed oyster shells that’s taking up room in my filter box.
Home Depot didn’t have the solar salt but Wal-Mart did, it’s a 40lb blue bag of Morton solar salt water softening crystals (is this the one to use). I’m not sure when to start using the salt, I have read that salt in very cold water will make the water feel colder for fish, thus the reason they use it to make ice cream. (Not sure how much truth) With that said it is going to be very cold here for at least 10 days, at what temp of the pond water should I start using the salt to keep my fish safe from nitrites. In your opinion what is the best ppt amount of salt to use and how many days should I keep it at that level without harming fish before I start to reduce it with water changes. Sorry about having so many questions about salt but, I’ve never used it before and 50 plus lbs of salt seams like a lot (scares me just a little).
In the meantime I’m testing the water every day for pH, KH and ammonia. I have the API ammonia test kit and I’m almost positive that I read on the instructions sheet (before I threw it away) that it was salicylate. If Nitrite, Nitrate or ammonia levels go up I am ready for water changes. One end of the drain hose is connected to the bottom of the filter box and the other end is out at the street, just open the valve and out with the old and in with the new.
And YOUR RIGHT, my goal period… is to never let this happen again! I’ve cried like a baby over losing my pets, they are to me like most people dogs are to them.
Thank you so much for your help,
Deb
Hi Deb!
Isn't this a great hobby? Aren't we having fun?
I think sensory overload is a mild term for what you have, so let's try to simplify things. First, I think if you back off and look at the whole problem, it might get a little easier to cope with.
pH crashes happen when the natural nitrifying action of your filter bacteria use up the carbonates dissolved in your water. As the buffering capacity of your pond decreases, the hydrogen ion (acid) liberated by the nitrifying process builds up, your pH drops (usually suddenly) and everything dies.
From that point, you have two necessary strategies:
1) Short-term, you need to restore as much buffer as you can as quickly as you can. You've already done this with the baking soda, and there's no real limit on how much you can use. While it will increase your dissolved solids load, it also acts a little like salt, but we'll talk about that later. Bicarb is not, by itself, a base. It's a buffer. It will raise the pH in the pond by soaking up the free hydrogen, but it won't push you so far into alkalinity so as to imperil your fish. Remember that for ammonia, low pH is protective. It ionizes the ammonia, rendering it less toxic. You run into trouble as the pH rises and the deionized ammonia levels increase. Your short-term solutions to this are water changes (done) and products like Amquel. The problem with Amquel and its cousins (ChlorAm-X and ProAm-X) is that they are pricey (especially when bought in a pet store!) and they also interfere with standard (Nessler reagent) ammonia test kits. They do a great job of taking the ammonia out and even deal with chlorine and chloramine, but you'll need a salicylate-method ammonia test kit to follow your ammonia levels until you can clear the Amquel out over time with water changes. To keep costs down, you can get ten-pound buckets of the powdered product as well as the LaMotte salicylate test kits from Aquatic Ecosystems (now Pentair Aquatics) in Apopka, FL. Your important measurements for the short term will be pH (7.2-7.5) , Ammonia (0) and alkalinity (KH- around 120 ppm). Forget GH, it has no value here.
2) You are correct in assuming that your filters are quite dead. You now have "new pond syndrome" all over again. You WILL HAVE a nitrite spike soon as your biofilters come back. Remember that the bacterial populations that do the ammonia-nitrite conversion show up a couple weeks before the nirtite-nitrate bugs. Nitrite is ferociously toxic, and your mid-range goal is to control this. First, feed sparingly, if at all. Second, water changes are your friend. Third, salt helps. A lot. This is about the only ponding scenario where salt has any value. Concentrations of 1.88ppt (1.5 lbs per 100 gal) to 3.8 ppt salt will keep the nitrite from binding to the piscine hemoglobin in your fish's blood and giving them the fishy equivalent of carbon monoxide poisoning in humans. As your bacterial populations restore themselves, you can wash the salt levels down with water changes. While you are ordering your ProAm-X, get a salt meter from Pentair, too. They cost around $40 and are a really good thing to have.
3) Salt is CHEAP! You just have to know what to buy. The "Solar Salt" in the 50 pound blue plastic bags at Home Despot or Menard's is just fine. "Pond salt" from the pet store is a ripoff. My article on Salt ("Oh Noes-More Salts") is up on the MPKS website.
4) Most "bacterial boosters" are useless. Either they have very little in the way of active biofiltration bugs, or they have the wrong ones. My expert at the Shedd Aquarium in Chicago, Alan LaPointe, says that the only additive worth using is a custom product that is sent fresh to big aquariums when they are preparing new aquatic habitats. The stuff he uses has a shelf life of about 2 days, but it works.The company (Fritz Products) started marketing a modified version of this product with a longer shelf-life last year. It's called Turbo Start 700 and you can get it from www.proaquatics .com (800-955-1323, ext 158.) It is still pricey and needs to be kept refrigerated and used quickly, but it works. Reliably.
5) Long-term, your goal is to NEVER LET THIS HAPPEN AGAIN! Given your location, you have a year-round ponding season, and even though you consider 40 F to be the deep freeze, your pond and your fish keep right on churning out the [H+] and the ammonia. For you, there is no time in the year when you can relax your vigilance on your water quality. The coral and the oyster shell are very slow releasers of calcium salts and do not work well in small-scale environments (i.e.: backyard ponds). A much more efficient solution to Alkalinity maintenance (besides frequent, year-round water testing) is the "pond puck". Go to your favorite craft store and get a big ol' box of Plaster of Paris. Mix up a batch of it and pour some into a bunch of empty margarine tubs. If this is just too low-class for you, you can use fancy Jell-O molds or whatever. When they have solidified, hide a few in your falls, skimmer and anywhere else the water moves. They'll dissolve over a week or two and maintain your alkalinity nicely. Cheap, too!
Ponding and koi keeping is one of the most challenging and absorbing hobbies in the Universe. It forces you to learn new things on a constant basis and rewards you with summers of tranquility and "good ch'i" (for all you fung shui fanatics out there). As a fellow prisoner of the Three Laws, I salute you!
Happier ponding!
Bob